All 11 players on each team scored their spot-kicks before Gabriel Suazo hit the post with his second attempt and Abdeljalil Sahloune netted to set up a last-16 tie with Monaco.
Toulouse had been moments away from going out in normal time. Omar Bezzekhami put Rouen, who were promoted to the Championnat National last season, ahead with Toulouse captain Vincent Sierro equalizing two minutes later.
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