Athletic were the aggressors throughout the first half against a harried Real Madrid who were short of ideas when in possession and toothless up front, going to the break with no shots on target.
However, the French forward, who missed a spot-kick in the Champions League loss at Liverpool last week, stroked another weak shot that made it easy for Julen Agirrezabala to palm the effort away.
Mbappé arrived with sky-high expectations to boost a stellar Real Madrid squad who won last season's LaLiga and Champions League titles, but so he has been a shadow of his old self, looking tentative and out of sync from the rest of the team.
It was another uninspired performance by Mbappé who has missed two of his five penalties for Real Madrid in all competitions, making him the LaLiga player who has failed to convert most penalties this season.
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