Britain open their campaign against Germany on November 15, with the winners to face defending champions Canada in the quarter-finals.
Captain Anne Keothavong said: 'We are really looking forward to the Finals in Malaga after qualifying following our fantastic weekend in France in April.'
Both Emma Raducanu and Katie Boulter are set to lead Great Britain at the Billie Jean King Cup Finals in Malaga in November.
This is the first time they have qualified on merit since the current format was introduced.
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