Can You Order A Caffeine-Free Espresso Martini At A Restaurant? - Tasting Table
Briefly

The specific combination of alcohol and caffeine can be less than stellar for our bodies. So, if you don't want a caffeine fix after dark, does that mean you can't enjoy this delicious, trendy tipple?
A shot of espresso has about 63 milligrams of caffeine, almost as much as an eight-ounce cup of coffee, which has around 95. When you order your espresso martini, simply ask for the decaf switch.
Decaf espresso tastes just as good as standard espresso, and you'd be saving yourself a big headache, literally. Both alcohol and caffeine dehydrate our bodies, so combining both doubles the dehydration.
Read at Tasting Table
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