Al Nassr overturned a 1-0 first leg deficit to win 4-3 on Monday but with the contest ending 4-4 on aggregate, the players headed into a shootout from which Al-Ain prevailed.
Al-Ain goalkeeper Khalid Eisa made amends for a disappointing display when he saved Brozovic's opening penalty and, with Soufiane Rahimi, Kaku and Sultan Al Shamsi all converting, Otavio's miss meant Al Nassr were eliminated.
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