Cristiano Ronaldo will become the first European player to make 50 major tournament appearances, having played 28 matches across the European Championship and 22 at the World Cup.
Forward Georges Mikautadze aims to join a select group by scoring all three of a side's initial goals in a competition.
Georgia must win against Portugal to progress to the round of 16 in their first major tournament.
Portugal has already clinched a spot in the next stage after victories in previous matches.
Georgia's potential opponents in the next stage depend on their final standing in the group.
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