Gianluca Scamacca's brace put the Italian outfit 2-0 up, and Atalanta had other chances outside of the two goals.
For the third goal, Scamacca would turn provider when he slipped through a teammate in on goal.
The effort was saved by Caoimhin Kelleher but Mario Pasalic was on hand to smack the ball home to a gaping goal.
Liverpool supporters have been left absolutely stunned on this awful Thursday evening at Anfield. They must find a way to get themselves back in this tie before heading to Italy for the second leg.
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