Villarreal's last season in La Liga ended in disappointment, finishing eighth and missing out on European qualification for the first time since 2018.
Atletico Madrid secured fourth place, ensuring their participation in the Champions League, and will look to maintain their status as one of Spain's top clubs.
Villarreal signed six new players after last season's struggles, hoping to strengthen their squad and reclaim a European spot.
Under coach Marcelino, Villarreal comes into this match after a disappointing pre-season, which included a heavy 4-0 defeat to Brighton.
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