The visitors wasted several chances before Pepe put them in front in the 30th minute with a close-range strike from a rebound, but Barca hit back quickly, with a fine curling shot into the top corner by Cancelo two minutes later.
Cancelo was excellent running down the left channel and teed up Joao Felix for a tidy first-time finish in the 57th minute to secure the win.
Barcelona are top of Group H on 12 points, three ahead Porto and Shakhtar Donetsk who will play each other on the final matchday to decide who will join Barca in the knockout stage.
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