The Nespresso Espresso Pods With The Highest Caffeine Content - Tasting Table
Briefly

"The answer is Vertuo Espresso Diavolitto, which boasts around 150 milligrams of caffeine per cup. For comparison, Nespresso's other espresso pods usually contain 50 to 100 milligrams of caffeine per cup, so Diavolitto comes with a significant boost."
"Therefore, caffeine content can differ even within the pods of the same line - that's why Nespresso is more comfortable discussing approximates and ranges rather than definite numbers."
"Diavolitto is definitely the most caffeinated single espresso pod, though. It's only compatible with Nespresso's Vertuo machines, which might be disappointing..."
"The double espresso pods also vary in caffeine content. Chiaro has the lowest caffeine content because it's only made with Arabica coffee (which contains up to 1.5% caffeine per bean)."
Read at Tasting Table
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