Hosts Real Madrid took the lead in the 10th minute when World Cup winner OIga Carmona's effort from range deflected wickedly off Chelsea defender Millie Bright to wrong-foot goalkeeper Ann-Katrin Berger and fly into the net.
But two minutes later Las Blancas were awarded a penalty, with Danish referee Frida Klarlund adjudging Jessie Fleming to have fouled Athenea del Castillo in the penalty area.
The goal was quickly ruled out for offside but, replays showed Charles had timed her run perfectly.
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