The 40-year-old right-hander hasn't pitched since last season.
Flexen will take the mound to start for the White Sox, his first of the season.
Braves will start Charlie Morton, who had a 3.64 ERA and ranked ninth in K/9 among qualified pitchers last season.
Chris Flexen, the White Sox's probable starting pitcher, finished last season with a 6.86 ERA and a 1.671 WHIP.
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