#copper-catalysis

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#deaminative-cross-coupling #amine-activation #boryl-radicals #late-stage-functionalization
fromwww.nature.com
6 days ago
Science

Deaminative cross-coupling of amines by boryl radical -scission

Native primary, secondary, and tertiary amines can be activated via borane coordination to generate boryl radicals for copper-catalyzed deaminative cross-coupling.
Science
fromwww.nature.com
4 weeks ago

Decoding the redox behaviour of copper in Ullmann-type coupling reactions

Cu(I) reacts with an electron-poor aryl iodide via a Cu(I)/Cu(III)/Cu(II)/Cu(III)/Cu(I) redox sequence culminating in C(sp2)-CF3 bond formation.
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