Each coin will feature a unique design linking to the films of that decade.
The first coin celebrating 007 in the 1960s depicts Sean Connery's Bond seated in Little Nellie, the gyroplane from the film You Only Live Twice.
Rebecca Morgan, director of commemorative coin at the Royal Mint, said: James Bond is Britain's favourite secret agent who has captivated audiences for over 60 years. We are delighted to be unveiling a new collectable coin range to celebrate 007's journey.
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