You can't mirror your iPhone while mirroring your Mac on Apple Vision Pro
Briefly

We've heard from knowledgeable sources that Apple's hardware only supports one of its Continuity mirroring features at the time. So if you're sending your Mac's screen to the Vision Pro, you won't be able to mirror your iPhone at the same time.
Mirroring a sharp and lag-free version of your Mac's screen is difficult enough - juggling that alongside a perfectly rendered copy of your iPhone might be too tough for some Macs.
Apple is already pushing beyond its current Continuity restrictions with visionOS 2, which will support higher resolution Mac mirroring, as well as the ability to virtualize an ultra-wide display.
It's not hard to imagine Apple bringing the iPhone mirroring feature directly to the Vision Pro eventually, but ideally, it would also work alongside Mac mirroring in the headset.
Read at Engadget
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